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978-3-8439-2921-9, Reihe Organische Chemie

Johannes Markus Wiest
Synthesis of Pyrroles and their Application in C-H Alkylation Chemistry

207 Seiten, Dissertation Technische Universität München (2016), Softcover, A5

Zusammenfassung / Abstract

A new synthetic procedure to access 3-cyanopyrroles was established. Two natural products, danaidal and suffrutine A, could be synthesized using this protocol. In addition, the role of pyrrole in the area of C-H activation was studied. It was found that pyrrole can act as a directing group in the palladium catalyzed C-H alkylation of various adjacent C(sp²)-H bonds.